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Units for Measuring Greenhouse Gases

In this publication, EIA reports information in forms that are most likely to be familiar to users of the document. Therefore, energy and industrial data are reported in their native units. For example, oil production is reported in thousand barrels per day, and energy production and sales are reported in British thermal units (Btu). For readers familiar with metric units, Btu can be a relatively intuitive unit because an exajoule is only 5 to 6 percent larger in energy content than a quadrillion Btu.

Emissions data are reported in metric units. This report uses the familiar “million metric tons” common in European industry instead of “gigagram,” which is equal to 1,000 metric tons and is the term favored by the scientific community. Metric tons are also relatively intuitive for users of English units, because a metric ton is only about 10 percent heavier than an English short ton.

Emissions of most greenhouse gases are reported here in terms of the full molecular weight of the gas (as in Table ES1). In Table ES2, however, and subsequently throughout the report, carbon dioxide and other greenhouse gases are reported in carbon dioxide equivalents. In the case of carbon dioxide, emissions denominated in the molecular weight of the gas or in carbon dioxide equivalents are the same. It is important to note that, in previous issues of this report, greenhouse gas emissions were reported in carbon equivalents. This change is being made to be consistent with the current trend, both domestically and internationally, to report greenhouse gas emissions in carbon dioxide equivalents.

Emissions of other greenhouse gases (such as methane) can also be measured in “carbon dioxide equivalent” units by multiplying their emissions (in metric tons) by their global warming potentials (GWPs). Carbon dioxide equivalents are the amount of carbon dioxide by weight emitted into the atmosphere that would produce the same estimated radiative forcing as a given weight of another radiatively active gas. Carbon dioxide equivalents are computed by multiplying the weight of the gas being measured (for example, methane) by its estimated GWP (which is 23 for methane). GWPs are discussed in the text box on page 6 of this Executive Summary.


Comparison of Global Warming Potentials from the IPCC’s Second and Third Assessment Reports

Comparison of 100-Year GWP Estimates
from the IPCC’s Second (1996) and Third (2001) Assessment Reports
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Gas 1996 IPCC GWP 2001 IPCC GWP
Methane 21 23
Nitrous Oxide 310 296
HFC-23 11,700 12,000
HFC-125 2,800 3,400
HFC-134a 1,300 1,300
HFC-143a 3,800 4,300
HFC-152a 140 120
HFC-227ea 2,900 3,500
HFC-236fa 6,300 9,400
Perfluoromethane (CF4) 6,500 5,700
Perfluoroethane (C2F6) 9,200 11,900
Sulfur Hexafluoride (SF6) 23,900 22,200

Global warming potentials (GWPs) are used to compare the abilities of different greenhouse gases to trap heat in the atmosphere. GWPs are based on the radiative efficiency (heat-absorbing ability) of each gas relative to that of carbon dioxide (CO2), as well as the decay rate of each gas (the amount removed from the atmosphere over a given number of years) relative to that of CO2. The GWP provides a construct for converting emissions of various gases into a common measure, which allows climate analysts to aggregate the radiative impacts of various greenhouse gases into a uniform measure denominated in carbon or carbon dioxide equivalents. The table at the right compares the GWPs published in the Second and Third Assessment Reports of the Intergovernmental Panel on Climate Change (IPCC).

In compiling its greenhouse gas emission estimates, EIA attempts to employ the most current data sources. For that reason, and because the IPCC is generally considered the authoritative source for GWPs, the GWP values from the IPCC’s Third Assessment Report are used in this report. It is important to point out, however, that countries reporting to the United Nations Framework Convention on Climate Change (UNFCCC), including the United States, have been compiling estimates based on the GWPs from the IPCC’s Second Assessment Report. The UNFCCC Guidelines on Reporting and Review, adopted before the publication of the Third Assessment Report, require emission estimates to be based on the GWPs in the IPCC Second Assessment Report. This will probably continue in the short term, until the UNFCCC reporting rules are changed. Following the current rules, the U.S. Environmental Protection Agency (EPA), which compiles the official U.S. emissions inventory for submission to the UNFCCC, intends to present estimates based on the GWPs published in the Second Assessment Report in its report, Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2002, scheduled for release in April 2004.

The table below shows U.S. carbon dioxide equivalent greenhouse gas emissions calculated using the IPCC’s 1996 (Second Assessment Report) and 2001 (Third Assessment Report) GWPs. The estimate for total U.S. emissions in 2002 is 0.6 percent higher when the revised GWPs are used. The estimates for earlier years generally follow the same pattern. Using the 2001 GWPs, estimates of carbon dioxide equivalent methane emissions are 9.5 percent higher, and carbon-equivalent nitrous oxide emissions are 4.5 percent lower. Carbon dioxide equivalent emissions of HFCs, PFCs, and SF6 are lower for some years and higher for others, depending on the relative shares of the three gases.

Comparison of Global Warming Potentials from the IPCC's Second and Third Assessment Reports (continued)
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Gas IPCC GWP Annual GWP-Weighted Emissions
(Million Metric Tons Carbon Dioxide Equivalent)
1990 2001 2002
1996 2001 1996 GWP 2001 GWP Percent Change 1996 GWP 2001 GWP Percent Change 1996 GWP 2001 GWP Percent Change
Carbon Dioxide 1 1 5,006 5,006 0.0 5,748 5,748 0.0 5,796 5,796 0.0
Methane 21 23 657 719 9.5 575 630 10.0 560 613 9.5
Nitrous Oxide 310 296 350 334 -4.5 353 337 -5.0 349 333 -4.5
HFCs, PFCs, and SF6 M M 101 97 -4.1 110 114 3.1 117 121 3.4
  Total 6,113 6,156 0.7 6,787 6,829 0.6 6,820 6,862 0.6

 

 

 

 

 

 

 

 

 

 

Released: October 2003