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1. U.S. Emissions of Greenhouse Gases in Perspective 

About This Report 

The Energy Information Administration (EIA) is required by the Energy Policy Act of 1992 to prepare a report on aggregate U.S. national emissions of greenhouse gases for the period 1987-1990, with annual updates thereafter. This report is the tenth annual update, covering national emissions over the period 1990-2001, with preliminary estimates of emissions for 2002. The methods used by EIA to estimate national emissions of greenhouse gases are subject to continuing review. As better methods and information become available, EIA revises both current and historical emissions estimates (see “What’s New in This Report”). Emissions estimates for carbon dioxide are reported in metric tons of carbon dioxide; estimates for other gases are reported in metric tons of gas (see “Units for Measuring Greenhouse Gases,” in the Executive Summary) and in carbon dioxide equivalent units where appropriate. Estimates of total national emissions in carbon dioxide equivalent units are shown in Table ES2. 

Chapter 1 of this report briefly summarizes some background information about global climate change and the greenhouse effect and discusses important recent developments in global climate change activities. Chapters 2 through 4 cover emissions of carbon dioxide, methane, and nitrous oxide, respectively. Chapter 5 focuses on emissions of engineered gases, including hydrofluorocarbons, perfluorocarbons, and sulfur hexafluoride. Chapter 6 describes potential sequestration and emissions of greenhouse gases as a result of land use changes. 

The Greenhouse Effect and Global Climate Change 

The Earth is warmed by radiant energy from the Sun. Over time, the amount of energy transmitted to the Earth’s surface is equal to the amount of energy re-radiated back into space in the form of infrared radiation, and the temperature of the Earth’s surface stays roughly constant; however, the temperature of the Earth is strongly influenced by the existence, density, and composition of its atmosphere. Many gases in the Earth’s atmosphere absorb infrared radiation re-radiated from the surface, trapping heat in the lower atmosphere. Without the natural greenhouse effect, it is likely that the average temperature of the Earth’s surface would be on the order of -19o Celsius, rather than the +14o Celsius actually observed.1 The gases that help trap the Sun’s heat close to the Earth’s surface are referred to as “greenhouse gases.” All greenhouse gases absorb infrared radiation (heat) at particular wavelengths. 

Table 1.  Global Atmospheric Concentrations of Selected Greenhouse Gases  
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Item  Carbon Dioxide  Methane  Nitrous Oxide Sulfur Hexafluoride  Perfluoromethane
(parts per million)  (parts per trillion) 
Pre-industrial (1750) Atmospheric Concentration  278  0.700  0.270  40 
1998 Atmospheric Concentration  365  1.745  0.314  4.2  80 
Average Annual Change, 1990-1999  1.5a  0.007a  0.0008  0.2  1.0 
Atmospheric Lifetime (Years)  50–200b  12c  114c  3,200 >50,000 

The most important greenhouse gases are water vapor (H2O), carbon dioxide (CO2), methane (CH4), nitrous oxide (N2O), and several engineered gases, such as hydrofluorocarbons (HFCs), perfluorocarbons (PFCs), and sulfur hexafluoride (SF6). Water vapor is by far the most common, with an atmospheric concentration of nearly 1 percent, compared with less than 0.04 percent for carbon dioxide. The effect of human activity on global watr vapor concentrations is considered negligible, however, and anthropogenic emissions of water vapor are not factored into national greenhouse gas emission inventories for the purposes of meeting the requirements of the United Nations Framework Convention on Climate Change (UNFCCC) or the Kyoto Protocol.2 Concentrations of other greenhouse gases, such as methane and nitrous oxide, are a fraction of that for carbon dioxide (Table 1). 

Scientists recognized in the early 1960s that concentrations of carbon dioxide in the Earth’s atmosphere were increasing every year. Subsequently, they discovered that atmospheric concentrations of methane, nitrous oxide, and many engineered chemicals also were rising. Because current concentrations of greenhouse gases keep the Earth at its present temperature, scientists began to postulate that increasing concentrations of greenhouse gases would make the Earth warmer. 

In computer-based simulation models, rising concentrations of greenhouse gases nearly always produce an increase in the average temperature of the Earth. Rising temperatures may, in turn, produce changes in weather and in the level of the oceans that might prove disruptive to current patterns of land use and human settlement, as well as to existing ecosystems. To date, however, it has proven difficult to disentangle the human impact on climate from normal temporal and spatial variations in temperature on a global scale. The most recent report of the Intergovernmental Panel on Climate Change (IPCC), an international assemblage of scientists commissioned by the United Nations to assess the scientific, technical, and socioeconomic information relevant for the understanding of the risk of human-induced climate change, estimates that the global average surface temperature has increased by 0.6o ± 0.2oC since the late 19th century.3 The IPCC goes on to conclude that: “There is new and stronger evidence that most of the warming observed over the last 50 years is attributable to human activities.”4 

In the aftermath of the IPCC report, the Domestic Policy Council, in May 2001 as part of its review of U.S. policy on climate change, requested that the National Academy of Sciences identify areas of uncertainty in the science of climate change, as well as review the IPCC report and summaries.5 The National Academy of Sciences commissioned the National Research Council to carry out this review. The National Research Council in issuing its findings appeared to agree with some of the IPCC conclusions, but also seemed to suggest that further work needs to be done in identifying the impacts of natural climatic variability and reducing the uncertainty inherent in climate change modeling. Among the National Research Council findings are the following:6 

Greenhouse gases are accumulating in Earth’s atmosphere as a result of human activities, causing surface air temperatures and subsurface ocean temperatures to rise. Temperatures are, in fact, rising. The changes observed over the last several decades are likely mostly due to human activities, but we cannot rule out that some significant part of these changes is also a reflection of natural variability. 

Because there is considerable uncertainty in current understanding of how the climate system varies naturally and reacts to emissions of greenhouse gases and aerosols, current estimates of the magnitude of future warming should be regarded as tentative and subject to future adjustments (either upward or downward). 

The committee generally agrees with the assessment of human-caused climate change presented in the IPCC Working Group I (WGI) scientific report, but seeks here to articulate more clearly the level of confidence that can be ascribed to those assessments and the caveats that need to be attached to them. 

While both the extent and consequences of human-induced global climate change remain uncertain, the threat of climate change has put in motion an array of efforts by the United States and other governments to find some mechanism for limiting the risk of climate change and ameliorating possible consequences. To date, efforts have focused primarily on identifying levels and sources of emissions of greenhouse gases and on possible mechanisms for reducing emissions or increasing sequestration of greenhouse gases. 

Global Sources of Greenhouse Gases 

Table 2.  Global Natural and Anthropogenic Sources and Absorption of Greenhouse Gases 
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Gas Sources  Absorption  Annual Increase in Gas
in the Atmosphere 
Natural Human-Made  Total 
Carbon Dioxide
(Million Metric Tons of Gas)a 
770,000  23,100 793,100 781,400 11,700
Methane
(Million Metric Tons of Gas)b 
239  359 598 576 22 
Nitrous Oxide
(Million Metric Tons of Gas)c
9.5  6.9  16.4  12.6  3.8

Most greenhouse gases have both natural and human-made emission sources. There are, however, significant natural mechanisms (land-based or ocean-based sinks) for removing them from the atmosphere. However, increased levels of anthropogenic (human-made) emissions have pushed the total level of greenhouse gas emissions (both natural and anthropogenic) above the natural absorption rates for these gases. This positive imbalance between emissions and absorption has resulted in the continuing growth in atmospheric concentrations of these gases. Table 2 illustrates the relationship between anthropogenic (human-made) and natural emissions and absorption of the principal greenhouse gases. 

Water Vapor. Water vapor, as noted above, is the most common greenhouse gas present in the atmosphere. It is emitted into the atmosphere in enormous volumes through natural evaporation from oceans, lakes, and soils and is returned to Earth in the form of rain and snow. As a natural emission generally beyond human control, water vapor has not been included in climate change options under the United Nations Framework Convention on Climate Change. The recent IPCC report, however, cites a possible positive feedback from increased water vapor formation due to increased warming caused by rising atmospheric CO2 concentrations.7 Elevated atmospheric temperatures increase the water-holding capability of the atmosphere. According to some of the IPCC emission scenarios, higher water vapor content could double the predicted atmospheric warming above what it would be if water vapor concentration stayed constant. These scenarios, however, have an element of uncertainty due to the possible countervailing effect of increased cloud formation, which can act to cool the planet by absorbing and reflecting solar radiation or warm the planet through the emission of long-wave radiation. According to the IPCC, increases in atmospheric temperatures would not necessarily result in increased concentrations of water vapor, because most of the atmosphere today is undersaturated. 

Carbon Dioxide. Carbon is a common element on the planet, and immense quantities can be found in the atmosphere, in soils, in carbonate rocks, and dissolved in ocean water. All life on Earth participates in the “carbon cycle,” by which carbon dioxide is extracted from the air by plants and decomposed into carbon and oxygen, with the carbon being incorporated into plant biomass and the oxygen released to the atmosphere. Plant biomass, in turn, ultimately decays (oxidizes), releasing carbon dioxide back into the atmosphere or storing organic carbon in soil or rock. There are vast exchanges of carbon dioxide between the ocean and the atmosphere, with the ocean absorbing carbon from the atmosphere and plant life in the ocean absorbing carbon from water, dying, and spreading organic carbon on the sea bottom, where it is eventually incorporated into carbonate rocks such as limestone. 

Records from Antarctic ice cores indicate that the carbon cycle has been in a state of imbalance for the past 200 years, with emissions of carbon dioxide to the atmosphere exceeding absorption. Consequently, carbon dioxide concentrations in the atmosphere have been steadily rising. According to the IPCC, before 1750, atmospheric carbon dioxide concentration was around 280 ± 10 parts per million for several thousand years. The IPCC goes on to say that the present carbon dioxide concentration has not been exceeded during the past 420,000 years, and likely not during the past 20 million years.8 

The most important natural sources of carbon dioxide are releases from the oceans (330 billion metric tons of carbon dioxide per year) and land (440 billion metric tons of carbon dioxide annually), including 220 billion metric tons of carbon dioxide from plant respiration, 202 billion metric tons of carbon dioxide from non-plant respiration (bacteria, fungi, and herbivores), and 15 billion metric tons of carbon dioxide from combustion of natural and human-made fires.9 Known anthropogenic sources (including deforestation) were estimated to account for about 29 billion metric tons of carbon dioxide per year during the 1989 to 1998 time period.10 The principal anthropogenic source is the combustion of fossil fuels, which accounts for about 80 percent of total anthropogenic emissions of carbon worldwide. Natural processes—primarily, uptake by the ocean and photosynthesis—absorb substantially all the naturally produced carbon dioxide and some of the anthropogenic carbon dioxide, leading to an annual net increase in carbon dioxide in the atmosphere of 11.4 to 12.1 billion metric tons.11 

Methane. Methane is also a common compound. The methane cycle is less well understood than the carbon cycle. Natural methane is released primarily by anaerobic decay of vegetation in wetlands, by the digestive tracts of termites in the tropics, by the ocean, and by leakage from methane hydrate deposits. The principal anthropogenic sources are leakages from the production of fossil fuels, human-promoted anaerobic decay in landfills, and the digestive processes of domestic animals. Anthropogenic sources are estimated to be 60 percent of total methane emissions.12 The main sources of absorption are thought to be tropospheric reactions with hydroxyl (OH) radicals that break down methane into CH3 and water vapor (506 million metric tons), stratospheric reactions with hydroxyl radicals and chlorine (40 million metric tons), and decomposition by  bacteria in soils (30 million metric tons). Known and unknown sources of methane are estimated to total 598 million metric tons annually; known sinks (i.e., absorption by natural processes) total about 576 million metric tons. The annual increase in methane concentration in the atmosphere accounts for the difference of 22 million metric tons.13 

Nitrous Oxide. The sources and absorption of nitrous oxide are much more speculative than those for other greenhouse gases. The principal natural sources are thought to be bacterial breakdown of nitrogen compounds in soils, particularly forest soils, fluxes from ocean upwellings, and stratospheric photo dissociation and reaction with electronically excited oxygen atoms. The primary human-made sources are enhancement of natural processes through application of nitrogen fertilizers, combustion of fuels (in fossil-fueled power plants and from the catalytic converters in automobiles), certain industrial processes (nylon and nitric acid production), biomass burning, and cattle and feedlots. Worldwide, estimated known sources of nitrous oxide total 16.4 million metric tons annually (6.9 million metric tons from anthropogenic sources), and known sinks total 12.6 million metric tons. The annual increase in concentrations in the atmosphere is thought to total 3.8 million metric tons.14 

Halocarbons and Other Gases. During the 20th century, human ingenuity created an array of “engineered” chemicals, not normally found in nature, whose special characteristics render them particularly useful. A particular family of engineered gases is the halocarbons. A halocarbon is a compound containing either chlorine, bromine, or fluorine and carbon. Halocarbons are powerful greenhouse gases. Halocarbons that contain bromine or chlorine also deplete the Earth’s ozone layer. One of the best-known groups of halocarbons is the chlorofluorocarbons (CFCs), particularly CFC-12, often known by its trade name, “Freon-12.” CFCs have many desirable features: they are relatively simple to manufacture, inert, nontoxic, and nonflammable. Because CFCs are chemically stable, once emitted, they remain in the atmosphere for hundreds or thousands of years. Because they are not found in nature, these molecules absorb reflected infrared radiation at wavelengths that otherwise would be largely unabsorbed, and they are potent greenhouse gases, with a direct radiative forcing effect hundreds or thousands of times greater, gram-per-gram, than that of carbon dioxide. 

Because of their long atmospheric lives, a portion of the CFCs emitted into the atmosphere eventually find their way into the stratosphere, where they can be destroyed by sunlight. This reaction, however, releases free chlorine atoms into the stratosphere, and the free chlorine atoms tend to combine with stratospheric ozone, which protects the surface of the Earth from certain wavelengths of potentially damaging solar ultraviolet radiation (ultraviolet radiation, for example, causes human and animal skin cancers). 

The threat posed by CFCs to the ozone layer has caused the United States and many other countries to commit themselves to phasing out the production of CFCs and their chemical cousins, hydrochlorofluorocarbons (HCFCs), pursuant to an international treaty, the 1987 Montreal Protocol. As use of CFCs has declined, many related chemicals have emerged as alternatives, including HCFCs and hydrofluorocarbons (HFCs). HCFCs are similar to CFCs, but they are more reactive and consequently have shorter atmospheric lives, with less effect on the ozone layer and smaller direct global warming effects. HCFCs are also being phased out, but over a longer time scale. The ozone-depleting substances with the most potential to influence climate, CFC-11, CFC-12 and CFC-113, are beginning to show reduced growth rates in atmospheric concentrations in the aftermath of the Montreal Protocol. The present radiative forcing of CFC-11 is about 0.065 watts per square meter, and that of CFC-12 is around 0.2 watts per square meter.15 

HFCs have no chlorine and consequently have no effect on the ozone layer, but they are powerful greenhouse gases. The three most prominent HFCs in the atmosphere today are HFC-23, HFC-134a, and HFC-152a. HFC-23 is formed as a byproduct of HCFC-22 production, which is being phased out under the Montreal Protocol. Although HFC-23 is very long-lived (260 years), the growth rate in its atmospheric concentration has begun to level off in accordance with reductions in HCFC-22 production. HFC-134a production was rare before 1990, but in 1994 HFC-134a was adopted as the standard motor vehicle air conditioning refrigerant in virtually all new cars made in America. HFC-134a has a lifetime of 13.8 years, and emissions have grown rapidly from near zero in 1990 to 0.034 million metric tons in 2002.16 HFC-152a emissions have risen steadily since about 1995, but its short lifetime of 1.4 years has kept concentration levels below 1 part per trillion. 

Another new class of engineered halocarbons is the perfluorocarbons (PFCs), which include perfluoromethane (CF4) and perfluoroethane (C2F6). PFCs are emitted as byproducts of aluminum smelting and are increasingly being used in the manufacture of semiconductors. They are powerful greenhouse gases and extremely long-lived. Perfluoromethane has 100-year global warming potential (GWP) of 5,700 and a lifetime in excess of 50,000 years. Perfluoroethane has a GWP of 11,900 and a lifetime of 10,000 years. Perfluoromethane is a naturally occurring compound in fluorites, and emissions from this source create a natural abundance of 40 parts per trillion in the atmosphere. Increases in anthropogenic emissions, growing at about 1.3 percent annually, have raised atmospheric concentrations to 80 parts per trillion.17 Perfluoroethane does not occur naturally in the atmosphere, and current concentrations (3.0 parts per trillion) are attributable to anthropogenic emissions, which are growing by 3.2 percent annually. Sinks for PFCs are photolysis and ion reactions in the mesosphere.18

Sulfur hexafluoride (SF6) is used as an insulator in utility-scale electrical equipment and as a cover gas in magnesium smelting. It is not a halocarbon, but it is a powerful greenhouse gas. SF6 has a 100-year GWP of 22,200 and a lifetime of 3,200 years. Like perfluoromethane, SF6 occurs naturally in fluorites, which produce a natural abundance of 0.01 parts per trillion in the atmosphere. Current atmospheric concentrations (3.0 parts per trillion) can be traced to anthropogenic emissions, which grew by approximately 7 percent annually during the 1980s and 1990s. Also like PFCs, sinks for SF6 are photolysis and ion reactions in the mesosphere. 

There may be other chemicals not yet identified that exhibit radiative properties similar to those of the halocarbons and other gases described above. One recent discovery identified trifluoromethyl sulfur pentafluoride (SF5CF3) as a new anthropogenic greenhouse gas in the atmosphere.19 It is believed that SF5CF3 is created by the breakdown of SF6 in high-voltage equipment, which produces CF3 that reacts with SF5 radicals resulting from high-voltage discharges. Its atmospheric concentration has grown from near zero in 1960 to 0.12 parts per trillion in 1999. To date, SF5CF3 has the largest radiative forcing on a per-molecule basis of any gas found in the atmosphere.20 The United Nations Framework Convention on Climate Change does not yet specifically address this gas. 

A number of chemical solvents are also strong greenhouse gases. The solvents carbon tetrachloride (GWP of 1,800 and lifetime of 35 years) and methyl chloroform (GWP of 140 and lifetime of 4.8 years), however, are regulated in the United States for the purposes of both ozone depletion and toxicity. All these gases have direct radiative forcing effects, which are offset to some degree by their ozone-depleting effects. 

With the advent of the United Nations Framework Convention and the Kyoto Protocol, the halocarbon and other industrial chemicals can be grouped into two categories: 

  • Ozone-depleting chemicals regulated under the Montreal Protocol but excluded from the Framework Convention (CFCs, HCFCs, and others) 
  • “Kyoto gases” (HFCs, PFCs, and SF6). 

The “Kyoto gases” are deemed to “count” for the purposes of meeting national obligations under the Framework Convention. The ozone depleters, however, are excluded from the Framework Convention because they are regulated by the Montreal Protocol. 

Other Important Radiative Gases. There are a number of additional gases and particles, resulting in part from human sources, that produce radiative forcing of the Earth’s climate but are not included under the Framework Convention or the Montreal Protocol. In general, these gases are short-lived, they have only indirect climate effects, or there is a fair amount of uncertainty about their climatic impacts. They can be broken down into three general classes: (1) ozone, both tropospheric and stratospheric; (2) criteria pollutants that are indirect greenhouse gases; and (3) aerosols, including sulfates and black soot. 

Ozone (O3) is present in both the troposphere and the stratosphere. Tropospheric ozone is not directly emitted into the atmosphere but instead forms through the photochemical reactions of various ozone precursors (primarily, nitrogen oxides and volatile organic compounds). In the troposphere, ozone acts as a direct greenhouse gas. The lifetime of ozone in the atmosphere varies from weeks to months, which imparts an element of uncertainty in estimating tropospheric ozone’s radiative forcing effects. The IPCC estimates that the radiative forcing of tropospheric ozone is 0.35 ± 0.2 watts per square meter.21 The depletion of stratospheric ozone due to the emission of halocarbons, on the other hand, has tended to cool the planet. The IPCC estimates that the cooling due to stratospheric ozone depletion is on the order of -0.15 ± 0.1 watts per square meter.22 As the ozone layer recovers, however, due to the impacts of the Montreal Protocol, it is expected that stratospheric ozone will exert a positive radiative forcing effect on the Earth’s climate. 

There are also a number of compounds (carbon monoxide, nitrogen oxides, and volatile organic compounds) that are indirect greenhouse gases. These gases are regulated in the United States pursuant to the Clean Air Act, and they are often referred to as “criteria pollutants.” They are emitted primarily as byproducts of combustion (both of fossil fuels and of biomass), and they influence climate indirectly through the formation of ozone and their effects on the lifetime of methane emissions in the atmosphere. Carbon monoxide, via its affects on hydroxyl radicals, can help promote the abundance of methane in the atmosphere, as well as increase ozone formation. Some IPCC model calculations indicate that 100 metric tons of carbon monoxide emissions is equivalent to the emissions of about 5 metric tons of methane.23 

Nitrogen oxides, including NO and NO2, influence climate by their impacts on other greenhouse gases. Nitrogen oxides not only promote ozone formation, they also impact (negatively) methane and HFC concentrations in the atmosphere. The deposition of nitrogen oxides could also reduce atmospheric carbon dioxide concentrations by fertilizing the biosphere.24 

Volatile organic compounds (VOCs), although they have some short-lived direct radiative-forcing properties, primarily influence climate indirectly via their promotion of ozone formation and production of organic aerosols. The main sources of global VOC emissions are vegetation (primarily tropical) (377 million metric tons carbon equivalent), fossil fuels (161 million metric tons carbon equivalent), and biomass burning (33 million metric ton carbon equivalent).25 

Aerosols, which are small airborne particles or droplets, also affect the Earth’s climate. Aerosols have both direct effects, through their ability to absorb and scatter solar and thermal radiation, and indirect effects, through their ability to modify the physical properties and amount of clouds. In terms of climate change, the most prominent aerosols are sulfates, fossil fuel black carbon aerosols (sometimes called “black soot”), fossil fuel organic carbon aerosols, and biomass-burning aerosols. 

One of the primary precursors of sulfates is sulfur dioxide (SO2), which is emitted largely as a byproduct from the combustion of sulfur-containing fossil fuels, particularly coal. Sulfur dioxide reacts in the air to form sulfate compounds. The major source of anthropogenic black soot and organic carbon aerosols is the burning of fossil fuels, primarily coal and diesel fuels. Biomass-burning aerosols are formed by the incomplete combustion of forest products. The IPCC estimates the direct radiative forcing for aerosols as follows: sulfates, -0.4 watts per square meter; black soot, +0.2 watts per square meter; fossil fuel organic carbon, -0.1 watts per square meter; and biomass-burning aerosols, -0.2 watts per square meter.26 Although the indirect climate effects of aerosols are uncertain, some preliminary evidence points to an indirect cooling effect due to cloud formation.27 

Relative Forcing Effects of Various Gases 

The ability of a greenhouse gas to affect global temperatures depends not only on its radiative or heat-trapping properties but also on its lifetime or stability in the atmosphere. Because the radiative properties and lifetimes of greenhouse gases vary greatly, comparable increases in the concentrations of different greenhouse gases can have vastly different heat-trapping effects. For example, among the “Kyoto gases,” carbon dioxide is the most prominent in terms of emissions, atmospheric concentration, and radiative forcing, but it is among the least effective as a greenhouse gas. Other compounds, on a gram-per-gram basis, appear to have much greater effects. 

There has been extensive study of the relative effectiveness of various greenhouse gases in trapping the Earth’s heat. Such research has led to the development of the concept of a “global warming potential,” or GWP. The GWP is intended to illustrate the relative impacts on global warming of a given gas relative to carbon dioxide over a specific time horizon. Over the past decade, the IPCC has conducted an extensive research program aimed at summarizing the effects of various greenhouse gases through a set of GWPs. The results of that work were originally released in 1995 in an IPCC report, Climate Change 1994,28 and subsequently updated in Climate Change 199529 and Climate Change 2001.30 

The calculation of a GWP is based on the radiative efficiency (heat-absorbing ability) of the gas relative to the radiative efficiency of the reference gas (carbon dioxide), as well as the removal process (or decay rate) for the gas relative to the reference gas over a specified time horizon. The IPCC, however, has pointed out that there are elements of uncertainty in calculating GWPs.31 The uncertainty takes several forms: 

  • The radiative efficiencies of greenhouse gases do not necessarily stay constant over time (as calculated in GWPs), particularly if the abundance of a gas in the atmosphere increases. Each gas absorbs radiation in a particular set of wavelengths, or “window,” in the spectrum. In some cases, where concentrations of the gas are low and no other gases block radiation in the same window, small emissions of the gas will have a disproportionate absorptive effect. However, if concentrations of the gas rise over time, a larger and larger portion of the total light passing through the “window” will already have been captured, and the marginal effects of additional emissions will not be as large. Therefore, the effect of an additional unit of emission of a gas that is relatively plentiful in the atmosphere, such as water vapor or carbon dioxide, tends to be less than that of a rare gas, such as sulfur hexafluoride. This “diminishing return” effect implies that increasing the concentration of a particular gas reduces the impact of additional quantities of that gas. Thus, the relative impacts of various gases will change as their relative concentrations in the atmosphere change. 
  • The lifetime of a greenhouse gas (used in GWP calculations), particularly carbon dioxide, is also subject to uncertainty. Various natural processes cause many greenhouse gases to decompose into other gases or to be absorbed by the ocean or ground. These processes can be summarized in terms of the “atmospheric lifetime” of a particular gas, or the period of time it would take for natural processes to remove a unit of emissions from the atmosphere. Some gases, such as CFCs, have very long atmospheric lifetimes, in the hundreds of years. Others, such as carbon monoxide, have lives measured in hours or days. Methane, which decays into carbon dioxide over a period of a few years, has a much larger short-run effect on global warming than does an equivalent amount of carbon dioxide; however, over longer and longer periods—from 10 years to 100 years to 500 years, for example—the differences between the GWPs of methane and carbon dioxide become less significant, because carbon dioxide has a longer atmospheric lifetime than methane. 
Table 3.  Numerical Estimates of Global Warming Potentials compared With Carbon Dioxide
(Kilogram of Gas per kilogram of Carbon Diioxide)  
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Gas  Lifetime
(Years) 
Direct Effect for Time Horizons of 
20 Years  100 Years  500 Years 
Carbon Dioxide  5 – 200a 
Methane  12 62  23 
Nitrous Oxide  114  275  296  156 
HFCs, PFCs, and Sulfur Hexafluoride 
  HFC-23  260  9,400  12,000  10,000 
  HFC-125  29 5,900  3,400  1,100 
  HFC-134a  13.8  3,300  1,300  400 
  HFC-152a  1.4  410  120  37 
  HFC-227ea  33 5,600  3,500 1,100 
  Perfluoromethane (CF4 50,000 3,900  5,700  8,900
  Perfluoroethane (C2F6 10,000  8,000  11,900  18,000 
  Sulfur Hexafluoride (SF6) 3,200  15,100 22,200  32,400

Table 3 summarizes the consensus results of the most recent studies by scientists working on behalf of the IPCC, showing estimates of atmospheric lifetimes and global warming potentials across various time scales. For the purposes of calculating “CO2 equivalent” units for this report, 100-year GWPs are used. 

The GWPs discussed above are direct GWPs in that they consider only the direct impact of the emitted gas. The IPCC has also devoted effort to the study of indirect GWPs. Indirect GWPs are based on the climatic impacts of the atmospheric decomposition of a gas into other gases. A number of gases—including methane, carbon monoxide, halocarbons, and nitrogen oxides—are thought to have indirect climatic effects. Methane indirectly influences the climate through ozone formation and the production of carbon dioxide. Carbon monoxide can promote ozone formation and extend the lifetime of methane in the atmosphere, which results in a positive indirect GWP. Some CFCs and HCFCs produce an indirect cooling effect by removing ozone from the stratosphere. The indirect cooling effect leads to lower net GWPs in a number of cases, but in most cases their net GWPs are still positive. Nitrogen oxides promote the formation of tropospheric ozone and, thus, have a positive indirect GWP—on the order of 5 for surface emissions and 450 for aircraft emissions.32 

International Developments in Global Climate Change 

Rising concentrations of carbon dioxide in the atmosphere were first detected in the early 1960s, and observations of atmospheric concentrations of methane, nitrous oxide, and other gases began in the late 1970s. Concern about the effects of rising atmospheric concentrations of greenhouse gases remained largely the province of atmospheric scientists and climatologists, however, until the mid-1980s, when a series of international scientific workshops and conferences began to move the topic onto the agenda of United Nations specialized agencies, particularly, the World Meteorological Organization (WMO). 

The IPCC was established under the auspices of the United Nations Environment Program and the WMO in late 1988, to accumulate available scientific research on climate change and to provide scientific advice to policymakers. A series of international conferences provided impetus for an international treaty aimed at limiting the human impact on climate. In December 1990, the United Nations established the Intergovernmental  Negotiating Committee (INC) for a Framework Convention on Climate Change. Beginning in 1991, the INC hosted a series of negotiating sessions that culminated in the adoption, by more than 160 countries, including the United States, of the Framework Convention on Climate Change (FCCC), opened for signature at the “Earth Summit” in Rio de Janeiro, Brazil, on June 4, 1992.33 

The objective of the Framework Convention is stated as follows: 

The ultimate objective of this Convention and any related legal instruments that the Conference of the Parties may adopt is to achieve, in accordance with the relevant provisions of the Convention, stabilization of greenhouse gas concentrations in the atmosphere at a level that would prevent dangerous anthropogenic interference with the climate system.34 

The Framework Convention divided its signatories into two groups: the countries listed in Annex I, and all others (Annex II). The Annex I countries include the 24 original members of the Organization for Economic Cooperation and Development (OECD) (including the United States), the European Union, and 14 countries  with economies in transition (Russia, Ukraine, and Eastern Europe).35 

The Convention requires all parties to undertake “policies and measures” to limit emissions of greenhouse gases, and to provide national inventories of emissions of greenhouse gases (Article 4.1a and b). Annex I parties are further required to take actions “with the aim of returning . . . to their 1990 levels these anthropogenic emissions of carbon dioxide and other greenhouse gases” (Article 4.2a and b). The signatories subsequently agreed that Annex I parties should provide annual inventories of greenhouse gas emissions. 

In April 1993, President Clinton committed to stabilizing U.S. emissions of greenhouse gases at the 1990 level by 2000, using an array of voluntary measures. In the following years, however, greenhouse gas emissions in the United States and many other Annex I countries continued to increase. The climate negotiators, continuing to meet as “the Conference of the Parties [to the Framework Convention]” (COP), took up the question of how to limit emissions in the post-2000 period, a topic on which the Framework Convention was silent. In 1995, COP-1, held in Berlin, Germany, agreed to begin negotiating a post-2000 regime. In 1996, COP-2, held in Geneva, Switzerland, agreed that the regime would encompass binding limitations on emissions for the parties, to be signed at COP-3, which was to be held in Kyoto, Japan, in December 1997. 

The Kyoto Protocol 

The most fundamental feature of the Kyoto Protocol to the Framework Convention, adopted on December 11, 1997, is a set of quantified greenhouse gas emissions targets for Annex I countries, which collectively are about 5 percent lower than the 1990 emissions of those countries taken as a group.36 Developing country signatories do not have quantified targets. Some of the key features of the Protocol are summarized below: 

  • Differentiated Targets. Each Annex I signatory has a “quantified emissions reduction limitation commitment,” which limits the signatory to some fraction, ranging from 90 to 110 percent, of its 1990 greenhouse gas emissions.37 Among other Annex I countries that have signed the Protocol, both the European Union (EU) and the individual members of the EU have signed and are responsible for meeting their commitments. 
  • Commitment Period. Each target is defined as the average of the signatory’s emissions over the 5-year period 2008-2012, called “the commitment period.” 
  • Six Gases. Participants are to limit their emissions of carbon dioxide, methane, nitrous oxide, HFCs, PFCs, and sulfur hexafluoride, weighted by the GWP of each gas. HFCs and PFCs are actually classes of gases with multiple members, but the term “six gases” has stuck. Participants may use 1995 as the baseline for HFCs, PFCs, and sulfur hexafluoride, instead of 1990. 
  • Demonstrable Progress. Annex I countries are required to have made “demonstrable progress” toward achieving their commitments by 2005. 
  • Land Use and Forestry. The Protocol includes complicated provisions on forestry, the implication being that some emissions and sequestration arising from changes in land use and forestry since 1990 can be counted against the target. 
  • Flexibility Mechanisms. The Protocol includes an array of methods by which Annex I countries can spread and reduce the cost of emissions limitations. The flexibility mechanisms include: 
  • Emissions Trading. Annex I countries can transfer portions of their quotas to one another. 
  • Joint Implementation. Annex I countries can undertake emissions reduction projects in other Annex I countries and receive a negotiated share of the emissions reductions generated by the projects. 
  • Joint Fulfillment. Like-minded Annex I countries (such as the EU) may band together to reallocate national targets within the group, so long as the collective target is met. 
  • Clean Development Mechanism. Annex I countries may undertake emissions reduction projects in non-Annex I countries and receive credits countable against national targets. 
  • Entry into Force. The Protocol enters into force when 55 countries and Annex I signatories with carbon dioxide emissions totaling 55 percent of total Annex I emissions “have deposited their instruments of ratification, acceptance, approval, or accession.” As of September 5, 2003, 117 countries have ratified or acceded to the Protocol. The Annex I nations that have ratified the Protocol represent 44.2 percent of total Annex I carbon dioxide emissions in 1990.38 

The U.S. Government formally signed the Kyoto Protocol on November 12, 1998. Under the U.S. Constitution, however, the Government may adhere to treaties only with the “advice and consent” of the Senate.39 In 2001, President Bush stated that he did not intend to submit the Protocol to the Senate for ratification and that the United States would not agree to the Kyoto Protocol because “it exempts 80 percent of the world, including major population centers such as China and India, from compliance, and would cause serious harm to the U.S. economy.”40 

U.S. Climate Change Initiatives 

As an alternative to the Kyoto Protocol, President Bush committed the U.S. Government to pursue a broad range of strategies to address the issues of global climate change by launching three initiatives: the Climate Change Research Initiative to accelerate science-based climate change policy development; the National Climate Change Technology Initiative to advance energy and sequestration technology development; and increased international cooperation to engage and support other nations on climate change and clean technologies.41 

Details of these initiatives were provided on February 14, 2002, when the President announced the Global Climate Change Initiative. This initiative calls on the United States to reduce its greenhouse gas intensity (total greenhouse gas emissions per unit of Gross Domestic Product) by 18 percent between 2002 and 2012 by voluntary measures. Under the Global Climate Change Initiative, the President directed the Secretary of Energy to propose improvements in the Department of Energy’s Voluntary Reporting of Greenhouse Gases Program. The improvements are to be designed to enhance the measurement accuracy, reliability and verifiability of emissions reductions reported to the Program. Reforms to the Program are to ensure that businesses and individuals that register reductions will not be penalized under any future climate policy, and to give transferable credits to companies that can show real emissions reductions.42,43 

On February 12, 2003, the U.S. Department of Energy, on behalf of President Bush, launched the President’s “Climate VISION” (Voluntary Innovative Sector Initiatives: Opportunities Now). Climate VISION is a voluntary, public-private partnership to pursue cost-effective initiatives to reduce the projected growth in U.S. greenhouse gas emissions. Climate VISION, to be administered through the Department of Energy, is intended to help meet the President’s goal of reducing U.S. greenhouse gas intensity by 18 percent by 2012. 

Climate VISION involves Federal agencies, including the Department of Energy, Environmental Protection Agency, Department of Agriculture, and Department of Transportation, working with industrial partners to voluntarily reduce greenhouse gas emissions over the next decade. Industry groups making commitments include the Alliance of Automobile Manufacturers, Aluminum Association, American Chemistry Council, American Forest and Paper Association, American Iron and Steel Institute, American Petroleum Institute, American Public Power Association, Association of American Railroads, Business Roundtable, Edison Electric Institute, Electric Power Supply Association, Magnesium Coalition and the International Magnesium Association, National Mining Association, National Rural Electric Cooperative Association, Nuclear Energy Institute, Portland Cement Association, and Semiconductor Industry Association. 

In July 2003, the Bush Administration also announced the U.S. Climate Change Strategic Plan. The Plan, to be implemented by the U.S. Climate Change Science Program, will organize the Federal Government’s climate change science research system, fund global climate observation research, and address some of the most complex questions and problems dealing with  long-term global climate variability and change. The Plan outlines the U.S. strategy for developing knowledge of variability and change in climate and related environmental and human systems.44 

Beyond the Kyoto Protocol 

Since the signing of the Kyoto Protocol, the signatories have continued to shape the “work in progress.” At the fourth session of the Conference of the Parties (COP-4) in Buenos Aires, Argentina, in November 1998, a plan of action was adopted to finalize a number of the implementation issues of the Protocol. Negotiations at the fifth Conference of the Parties (COP-5) in Bonn, Germany, from October 25 through November 5, 1999, focused on developing rules and guidelines for emissions trading, joint implementation, and a Clean Development Mechanism (CDM), negotiating the definition and use of forestry activities and additional sinks, and understanding the basics of a compliance system, with an effort to complete this work at the sixth Conference of the Parties (COP-6) at The Hague, Netherlands, in November 2000. 

The major goals of the COP-6 negotiations were to develop the concepts in the Protocol in sufficient detail that the Protocol could be ratified by enough Annex I countries to be put into force, and to encourage significant action by the non-Annex I countries to meet the objectives of the Framework Convention.45 The COP-6 negotiations focused on a range of technical issues, including emissions reporting and review, communications by non-Annex I countries, technology transfer, and assessments of capacity needs for developing countries and countries with economies in transition. 

The COP-6 negotiations were suspended in November 2000 without agreement on a number of issues, including the appropriate amount of credit for carbon sinks, such as forests and farmlands, and the use of flexible mechanisms, such as international emissions trading  and the CDM, to reduce the cost of meeting the global emissions targets.46 

The COP-6 negotiations resumed in Bonn, Germany, on July 16, 2001 (COP-6 Part 2), again to focus on developing the concepts in the Protocol in sufficient detail that it could be ratified by enough Annex I countries to be put into force. On July 23, 2001, 178 members/nations of the United Nations Framework Convention on Climate Change reached an agreement (the “Bonn Agreement”) on the operational rulebook for the Kyoto Protocol. 

The “Bonn Agreement” creates a Special Climate Change Fund and a Protocol Adaptation Fund to help developing countries adapt to climate change impacts, obtain clean technologies, and limit the growth in their emissions; allows developed nations to use carbon sinks to comply, in part, with their Kyoto Protocol emission reduction commitments; and establishes rules for the CDM, emissions trading, and Joint Implementation projects. The Bonn Agreement also emphasizes that domestic actions shall constitute a significant element of emission reduction efforts made by each Party and, also, establishes a Compliance Committee with a facilitative branch and an enforcement branch. In terms of compliance, for every ton of gas that a country emits over its target, it will be required to reduce an additional 1.3 tons during the Protocol’s second commitment period, which starts in 2013. 

The Bonn Agreement was forwarded for official adoption at the Seventh Session of the Conference of the Parties (COP-7), which was held in Marrakech, Morocco, from October 29 to November 9, 2001. On November 9, 2001, 165 nations reached agreement on a number of implementation rules for the Bonn Agreement and the Kyoto Protocol. The agreement, referred to as the “Marrakech Accords,” covered a number of issues, including: (1) rules for international emissions trading; (2) a compliance regime to enforce emissions targets, with the issue of legally binding targets deferred to a future Conference; (3) fungible accounting rules that  allow emissions trading among Annex I nations, as well as CDM and Joint Implementation mechanisms; and (4) a new emission unit for carbon sinks that cannot be banked for future commitment periods.47 

COP-8 met from October 23 to November 1, 2002, in New Delhi, India.48 COP-8 focused on technical issues related to the development of rules for Clean Development Mechanisms, reporting guidelines, and compliance under the Kyoto Protocol. In addition, COP-8 adopted guidance for funds managed by the Global Environmental Facility to be used in assisting developing countries. COP-9 is scheduled for December 1-12, 2003, in Milan, Italy. 

The Bush Administration has indicated that it has no objection to the participation of other countries in the Kyoto Protocol, even without U.S. participation. As mentioned above, the Administration has indicated that it intends to develop U.S. alternatives to the Kyoto Protocol, including the National Climate Change Technology Initiative, the Climate Change Research Initiative, and the Global Climate Change Initiative. As noted earlier, the Protocol can enter into force with ratification by at least 55 parties to the Protocol, accounting for 55 percent of total Annex I carbon dioxide emissions in 1990. Because the United States accounts for about 35 percent of 1990 Annex I carbon dioxide emissions, the Protocol can enter into force without U.S. ratification. 

 

Notes and Sources

Released: October 2003